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Effect of solvent on the hydrogenation of 4-phenyl-2-butanone over Pt based catalysts


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Authors

McManus, I 
Daly, H 
Thompson, JM 
Connor, E 
Hardacre, C 

Abstract

In part I of this study, experimental data were presented for the hydrogenation of 4-phenyl-2-butanone with a 4% Pt/TiO2 catalyst where the reaction rate and selectivity (ketone vs. aromatic ring) varied with solvent. In this paper, a rigorous kinetic model is presented utilising these data, incorporating statistical analysis methods to strengthen the foundations of mechanistically sound kinetic models. A fundamental kinetic model for the system is presented and a 2-site model was determined to be most appropriate, describing aromatic hydrogenation (postulated to be over a platinum site) and ketone hydrogenation (at the platinum titania interface). Solvent choice has little impact on the ketone hydrogenation rate constant but strongly impacts aromatic hydrogenation due to solvent-catalyst interaction. Reaction selectivity is also correlated to a fitted product adsorption constant parameter. This kinetic analysis method is the first of its kind demonstrating the role of solvents in influencing reactant adsorption and reaction selectivity.

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Keywords

Selective hydrogenation, Solvent effect, Aromatic ketone, Pt, Titania

Journal Title

Journal of Catalysis

Conference Name

Journal ISSN

0021-9517
1090-2694

Volume Title

330

Publisher

Elsevier BV
Sponsorship
Engineering and Physical Sciences Research Council (EP/G011397/1)
We acknowledge EPSRC for funding as part of the CASTech grant (EP/G011397/1) and the Department of Employment and Learning for a studentship (IM). NSB was funded by a PhD scholarship from the University of Birmingham. SKW was supported by an Engineering Doctorate Studentship in Formulation Engineering at the University of Birmingham sponsored by the EPSRC (EP/G036713/1) and Johnson Matthey.