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Oxygen Degradation in Mesoporous Al2O3/CH3NH3PbI3-xClx Perovskite Solar Cells: Kinetics and Mechanisms


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Authors

Pearson, AJ 
Eperon, GE 
Hopkinson, PE 
Habisreutinger, SN 
Wang, JTW 

Abstract

jats:pThe rapid pace of development for hybrid perovskite photovoltaics has recently resulted in promising figures of merit being obtained with regard to device stability. Rather than relying upon expensive barrier materials, realizing market‐competitive lifetimes is likely to require the development of intrinsically stable devices, and to this end accelerated aging tests can help identify degradation mechanisms that arise over the long term. Here, oxygen‐induced degradation of archetypal perovskite solar cells under operation is observed, even in dry conditions. With prolonged aging, this process ultimately drives decomposition of the perovskite. It is deduced that this is related to charge build‐up in the perovskite layer, and it is shown that by efficiently extracting charge this degradation can be mitigated. The results confirm the importance of high charge‐extraction efficiency in maximizing the tolerance of perovskite solar cells to oxygen.</jats:p>

Description

Keywords

perovskite, photovoltaic, lifetime, oxygen, stability

Journal Title

Advanced Energy Materials

Conference Name

Journal ISSN

1614-6832
1614-6840

Volume Title

6

Publisher

Wiley
Sponsorship
Engineering and Physical Sciences Research Council (EP/J017361/1)
This work was supported by SABIC and by the EPSRC, including by the Supergen Supersolar Consortium (EP/J017361/1) and the European Union Seventh Framework Program [FP7 2007-2003] under grant agreement 604032 of the MESO project. GE is supported by the EPSRC and Oxford Photovoltaics Ltd. through a Nanotechnology KTN CASE award. JW acknowledges the Swire Educational Trust for supporting his D.Phil. study at Oxford. We thank Sian Dutton (University of Cambridge) for access to XRD facilities and Felix Deschler (University of Cambridge) for helpful discussions.