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Effect of individual discharge cascades on the microstructure of plasma electrolytic oxidation coatings

Published version
Peer-reviewed

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Authors

Troughton, SC 
Nominé, A 
Dean, J 
Clyne, TW 

Abstract

Short duration (~1 s) PEO treatments have been applied to aluminium alloy samples on which coatings of thickness ~100 μm had previously been created. This was done using the small area electrical monitoring system previously developed in the Gordon Laboratory in Cambridge. Voltage supply frequencies of 50 Hz and 2.5 kHz were employed. Fairly high resolution SEM micrographs were taken, covering the whole surface of small area samples (ie over a circular area of diameter about 0.9 mm). This was done both before and after the 1 s PEO treatments. X-ray tomographic data were also obtained in the vicinity of a recently-completed set of discharges. The outcomes of these observations were correlated with synchronised high speed electrical monitoring and video photography, carried out during the PEO treatment periods. Localised cascades (comprising hundreds of individual discharges) were observed in all cases, persisting throughout the 1 s periods and also reappearing in the same location when a second 1 s PEO treatment was applied to the same sample. This repetition of discharges at the same location is apparently due to the deep pores associated with these sites, creating a pathway of low electrical resistance, even after appreciable oxidation has occurred in the vicinity. Observations were made of the way in which the surfaces were reconstructed locally as discharge cascades occurred. With the high frequency voltage supply, discharge lifetimes were limited to the half-cycle period (of 200 μs), but in other respects the cascades were similar to those with the lower frequency. However, some discharges occurred during cathodic half-cycles with the high frequency supply, at the same location as the anodic discharges in the cascade concerned.

Description

Keywords

Plasma electrolytic oxidation, Electrical discharge, High speed photography, X-ray tomography, Microstructure

Journal Title

Applied Surface Science

Conference Name

Journal ISSN

0169-4332
1873-5584

Volume Title

389

Publisher

Elsevier BV
Sponsorship
Engineering and Physical Sciences Research Council (EP/I001174/1)
Engineering and Physical Sciences Research Council (Grant ID: EP/I001174/1), Sims Scholarship, Keronite plc, Fundacion Banco Santander (Research Mobility Scholarship)