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Theory of edge-state optical absorption in two-dimensional transition metal dichalcogenide flakes

Accepted version
Peer-reviewed

Type

Article

Change log

Authors

Trushin, M 
Kelleher, EJR 

Abstract

We develop an analytical model to describe sub-band-gap optical absorption in two-dimensional semiconducting transition metal dichalcogenide (s-TMD) nanoflakes. The material system represents an array of few-layer molybdenum disulfide crystals, randomly orientated in a polymer matrix. We propose that optical absorption involves direct transitions between electronic edge states and bulk bands, depends strongly on the carrier population, and is saturable with sufficient fluence. For excitation energies above half the band gap, the excess energy is absorbed by the edge-state electrons, elevating their effective temperature. Our analytical expressions for the linear and nonlinear absorption could prove useful tools in the design of practical photonic devices based on s-TMDs.

Description

Keywords

cond-mat.mes-hall, cond-mat.mes-hall, cond-mat.mtrl-sci

Journal Title

Physical Review B

Conference Name

Journal ISSN

2469-9950
2469-9969

Volume Title

94

Publisher

American Physical Society
Sponsorship
Royal Academy of Engineering, Collaborative Research Center 767