Laser-induced reduction and in-situ optical spectroscopy of individual plasmonic copper nanoparticles for catalytic reactions
Accepted version
Peer-reviewed
Repository URI
Repository DOI
Change log
Authors
Di Martino, Giuliana https://orcid.org/0000-0001-5766-8384
Turek, V
Braeuninger-Weimer, Philipp https://orcid.org/0000-0001-8677-1647
Hofmann, Stephan https://orcid.org/0000-0001-6375-1459
Baumberg, Jeremy https://orcid.org/0000-0002-9606-9488
Abstract
Copper (Cu) can provide an alternative to gold (Au) for the development of efficient, low-cost and low-loss plasmonic nanoparticles (NPs), as well as selective nanocatalysts. Unlike Au, the surface oxidation of Cu NPs can be an issue restricting their applicability. Here, we selectively reduce the Cu NPs by low power laser illumination in vacuum and use dark-field scattering to reveal in real time the optical signatures of the reduction process and its influence on the Cu NP plasmonic resonance. We then study reactive processes at the single particle level, using individual Cu catalyst nanoparticles for the selective laser-induced chemical vapour deposition of germanium nanostructures.
Description
Keywords
40 Engineering, 4018 Nanotechnology, Nanotechnology, Bioengineering
Journal Title
Applied Physics Letters
Conference Name
Journal ISSN
0003-6951
1077-3118
1077-3118
Volume Title
110
Publisher
American Institute of Physics
Publisher DOI
Sponsorship
European Research Council (279342)
Engineering and Physical Sciences Research Council (EP/K016636/1)
European Research Council (320503)
Engineering and Physical Sciences Research Council (EP/G060649/1)
Engineering and Physical Sciences Research Council (EP/L027151/1)
Engineering and Physical Sciences Research Council (EP/G037221/1)
Engineering and Physical Sciences Research Council (EP/K016636/1)
European Research Council (320503)
Engineering and Physical Sciences Research Council (EP/G060649/1)
Engineering and Physical Sciences Research Council (EP/L027151/1)
Engineering and Physical Sciences Research Council (EP/G037221/1)
EPSRC Grant Nos. EP/G060649/1, EP/L027151/1, and EP/G037221/1, ERC Grant No. LINASS 320503, and ERC grant InsituNANO 279342