H2 production from partial oxidation of CH4 by Fe2O3 -supported Ni-based catalysts in a plasma-assisted packed bed reactor
Accepted version
Peer-reviewed
Repository URI
Repository DOI
Change log
Authors
Zheng, Yaoyao https://orcid.org/0000-0001-9502-4512
Grant, Rob
Hu, Wenting
Marek, Ewa https://orcid.org/0000-0002-8318-2131
Scott, Stuart A
Abstract
H2-rich gas production from CH4 at mild temperature (673 K), was achieved in a single step without introducing a separate oxygen stream. This was conducted in a plasma-assisted packed bed reactor in the presence of Ni-based catalysts doped on an active support, i.e. Fe2O3. Among the tested materials, NiO/Fe2O3 was found to be very promising and its excellent catalytic properties seemed to be induced by the presence of Fe2O3, which suppressed the formation of deposited carbon, and thus maintained the catalytic effect of metallic Ni (formed during NiO reduction by the CH4/Ar plasma). This work demonstrates the potential of plasma-assisted chemical looping partial oxidation for H2 production.
Description
Keywords
Plasma, Chemical looping, H(2 )production, Catalyst
Journal Title
PROCEEDINGS OF THE COMBUSTION INSTITUTE
Conference Name
Journal ISSN
1540-7489
1873-2704
1873-2704
Volume Title
37
Publisher
Elsevier BV