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Bulk properties of the van der Waals hard ferromagnet VI3

Published version
Peer-reviewed

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Authors

Son, S 
Coak, MJ 
Lee, N 
Kim, J 
Kim, TY 

Abstract

We present comprehensive measurements of the structural, magnetic, and electronic properties of layered van der Waals ferromagnet VI3 down to low temperatures. Despite belonging to a well-studied family of transition-metal trihalides, this material has received very little attention. We outline, from high-resolution powder x-ray diffraction measurements, a corrected room-temperature crystal structure to that previously proposed and uncover a structural transition at 79 K, also seen in the heat capacity. Magnetization measurements confirm VI3 to be a hard ferromagnet (9.1 kOe coercive field at 2 K) with a high degree of anisotropy, and the pressure dependence of the magnetic properties provide evidence for the two-dimensional nature of the magnetic order. Optical and electrical transport measurements show this material to be an insulator with an optical band gap of 0.67 eV - the previous theoretical predictions of d-band metallicity then lead us to believe VI3 to be a correlated Mott insulator. Our latest band-structure calculations support this picture and show good agreement with the experimental data. We suggest VI3 to host great potential in the thriving field of low-dimensional magnetism and functional materials, together with opportunities to study and make use of low-dimensional Mott physics.

Description

Keywords

cond-mat.str-el, cond-mat.str-el, cond-mat.mtrl-sci

Journal Title

Physical Review B: Condensed Matter and Materials Physics

Conference Name

Journal ISSN

1098-0121
2469-9969

Volume Title

99

Publisher

American Physical Society
Sponsorship
Engineering and Physical Sciences Research Council (EP/M000524/1)
EPSRC (1805371)