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A Peeling Approach for Integrated Manufacturing of Large Monolayer h-BN Crystals.

Accepted version
Peer-reviewed

Type

Article

Change log

Authors

Purdie, David G 
Fan, Ye 
Massabuau, Fabien C-P  ORCID logo  https://orcid.org/0000-0003-1008-1652
Braeuninger-Weimer, Philipp  ORCID logo  https://orcid.org/0000-0001-8677-1647

Abstract

Hexagonal boron nitride (h-BN) is the only known material aside from graphite with a structure composed of simple, stable, noncorrugated atomically thin layers. While historically used as a lubricant in powder form, h-BN layers have become particularly attractive as an ultimately thin insulator, barrier, or encapsulant. Practically all emerging electronic and photonic device concepts currently rely on h-BN exfoliated from small bulk crystallites, which limits device dimensions and process scalability. We here focus on a systematic understanding of Pt-catalyzed h-BN crystal formation, in order to address this integration challenge for monolayer h-BN via an integrated chemical vapor deposition (CVD) process that enables h-BN crystal domain sizes exceeding 0.5 mm and a merged, continuous layer in a growth time of less than 45 min. The process makes use of commercial, reusable Pt foils and allows a delamination process for easy and clean h-BN layer transfer. We demonstrate sequential pick-up for the assembly of graphene/h-BN heterostructures with atomic layer precision, while minimizing interfacial contamination. The approach can be readily combined with other layered materials and enables the integration of CVD h-BN into high-quality, reliable 2D material device layer stacks.

Description

Keywords

2D materials, CVD, catalyst, graphene, h-BN, heterostructures, platinum, transfer

Journal Title

ACS Nano

Conference Name

Journal ISSN

1936-0851
1936-086X

Volume Title

13

Publisher

American Chemical Society (ACS)
Sponsorship
European Research Council (279342)
Engineering and Physical Sciences Research Council (EP/M507751/1)
Engineering and Physical Sciences Research Council (EP/P00945X/1)
Engineering and Physical Sciences Research Council (EP/K016636/1)
European Commission Horizon 2020 (H2020) Marie Sk?odowska-Curie actions (656870)
Engineering and Physical Sciences Research Council (EP/L016087/1)
Engineering and Physical Sciences Research Council (EP/M506485/1)