Host-Guest Systems and Their Derivatives Based on Metal-Organic Frameworks
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Including guest compounds inside the pores of nanoporous crystalline hosts (e.g. zeolite) is a key strategy to post-synthetically functionalise these nanoporous materials over past half a century. It yields highly active and stable heterogeneous catalysts as well as robust materials with tuneable photoluminescence properties due to geometric/quantum confinement. More recently, metal-organic frameworks (MOFs), which are hybrid hosts assembled with metal centres and organic ligands, start to be considered for creating host-guest composites. Apart from the aforementioned confinement effects, MOFs with diverse chemistries as hosts can give rise to a variety of host-guest interactions in these composite systems. It is, however, challenging to investigate these MOF-guest systems due to small MOF pore dimensions, MOF instability, poor guest loading control and limitations in guest characterisations.
The thesis explores three different MOF-guest systems covering their preparation, characterisation as well as some unusual behaviour owing to MOF-guest interactions and/or confinement effects. The first system is incorporating electrically conducting poly(3,4-ethylenedioxythiophene) (PEDOT) into a
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Smoukov, Stoyan
Cheetham, Anthony