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Inter-ligand energy transfer in dye chromophores attached to high bandgap SiO2 nanoparticles.

Accepted version
Peer-reviewed

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Type

Article

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Authors

Price, Michael B 
Paton, Andrew 
Wagner, Isabella 
Laufersky, Geoffry 

Abstract

Artificial light harvesters require ordered arrangement of chromophores. We covalently attach three organic chromophore ligands to silicon dioxide nanoparticles. This allows us to study inter-ligand energy transfer when attached to SiO2 nanoparticles, creating a simple system with a large ratio of donors to acceptors. Using steady-state and transient spectroscopy measurements we quantify this energy transfer between ligands. We show a maximum transfer efficiency of 30% and measure the 2D diffusion length of anthracene carboxylic acid on SiO2 to be between 0.6 and 2.2 nm.

Description

Keywords

0306 Physical Chemistry (incl. Structural), 0299 Other Physical Sciences, Nanotechnology, Bioengineering

Journal Title

Chem Commun (Camb)

Conference Name

Journal ISSN

1359-7345
1364-548X

Volume Title

55

Publisher

Royal Society of Chemistry (RSC)

Rights

All rights reserved
Sponsorship
European Research Council (670405)