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Manipulating Color Emission in 2D Hybrid Perovskites by Fine Tuning Halide Segregation: A Transparent Green Emitter.

Published version
Peer-reviewed

Type

Article

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Authors

Zanetta, Andrea 
Andaji-Garmaroudi, Zahra 
Pirota, Valentina 
Pica, Giovanni 
Kosasih, Felix Utama 

Abstract

Halide perovskite materials offer an ideal playground for easily tuning their color and, accordingly, the spectral range of their emitted light. In contrast to common procedures, this work demonstrates that halide substitution in Ruddlesden-Popper perovskites not only progressively modulates the bandgap, but it can also be a powerful tool to control the nanoscale phase segregation-by adjusting the halide ratio and therefore the spatial distribution of recombination centers. As a result, thin films of chloride-rich perovskite are engineered-which appear transparent to the human eye-with controlled tunable emission in the green. This is due to a rational halide substitution with iodide or bromide leading to a spatial distribution of phases where the minor component is responsible for the tunable emission, as identified by combined hyperspectral photoluminescence imaging and elemental mapping. This work paves the way for the next generation of highly tunable transparent emissive materials, which can be used as light-emitting pixels in advanced and low-cost optoelectronics.

Description

Keywords

2D perovskites, halide mixtures, light emission, segregation, transparent light-emitting devices, tunability

Journal Title

Adv Mater

Conference Name

Journal ISSN

0935-9648
1521-4095

Volume Title

Publisher

Wiley
Sponsorship
European Research Council (756962)
Engineering and Physical Sciences Research Council (EP/R023980/1)
Royal Society (UF150033)
EPSRC (2127077)