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3D Printing of Liquid Crystalline Hydroxypropyl Cellulose—toward Tunable and Sustainable Volumetric Photonic Structures

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Peer-reviewed

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Article

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Abstract

Additive manufacturing is becoming increasingly important as a flexible technique for a wide range of products, with applications in the transportation, health, and food sectors. However, to develop additional functionality it is important to simultaneously control structuring across multiple length scales. In 3D printing, this can be achieved by employing inks with intrinsic hierarchical order. Liquid crystalline systems represent such a class of self-organizing materials, however, to date they have only been used to create filaments with nematic alignment along the extrusion direction. In this study, cholesteric hydroxypropyl cellulose (HPC) was combined with in situ photo-crosslinking to produce filaments with an internal helicoidal nanoarchitecture, enabling the direct ink writing of solid, volumetric objects with structural color. The iridescent color can be tuned across the visible spectrum by exploiting either the lyotropic or thermotropic behavior of HPC during the crosslinking step, allowing objects with different colors to be printed from the same feedstock. Furthermore, by examining the microstructure after extrusion, the role of shear within the nozzle was revealed and a mechanism proposed based on rheological measurements simulating the nozzle extrusion. Finally, by using only a sustainable biopolymer and water, a pathway towards environmentally friendly 3D printing is revealed.

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Journal Title

Advanced Functional Materials

Conference Name

Journal ISSN

1616-301X
1616-3028

Volume Title

Publisher

Wiley
Sponsorship
Biotechnology and Biological Sciences Research Council (BB/K014617/1)
European Research Council (639088)
European Research Council (790518)
European Commission Horizon 2020 (H2020) ERC (963872)
European Research Council (758865)
EPSRC (2111141)
European Commission Horizon 2020 (H2020) Marie Sk?odowska-Curie actions (722842)
This work was funded additionally by a Croucher Cambridge International Scholarship to C.L.C.C.; by a WD Armstrong Trust Studentship and a Macao Postgraduate Scholarship to I.M.L.
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