This data is related to the measurement of diffusion coefficients of species in porous carbon materials through an in situ NMR technique. The data provided here consists in: - electrochemistry measurements data (classical cyclic voltammetry for the supercapacitors outside of the NMR setup, and chronoamperometry for the supercapacitors while doing in situ NMR) - NMR measurements data (exchange spectroscopy and Pulse Field Gradient NMR) - SEM images - Sorption isotherms (used for the determination of the pore size distributions) - The electrochemistry data can be opened using EC-Lab or a text file editor. - The NMR data can be opened using TopSpin or a text file editor. - SEM images are included in a powerpoint file. - Sorption isotherms can be opened using a text file editor.