Origin files: Absorption and Photoluminescence (PL) spectra Abs_PL.opj Excitation energy dependent PL spectra exc_dep_PL.opj Excitation energy dependent transient absorption (TA) spectra exc_dep_GA.opj X-ray diffraction pattern XRD_TIPS-Tc.opj Data files [Dtc, cor (in-house data format prcessable in Matlab)] Vis and NIR TA spectrum (532 nm excitation) in ps time delays (ST) film_532exc_Vis_ST.Dtc,TIPS_tet_Gel_532exc_NIR_ST.Dtc Vis and NIR TA spectrum (500 nm excitation) in ps time delays (ST) film_500exc_Vis_ST.Dtc, TIPS_tet_Gel_500exc_NIR_ST.Dtc Vis and NIR TA spectrum (480 nm excitation) in ps time delays (ST) film_480exc_Vis_ST.Dtc, TIPS_tet_Gel_480exc_NIR_ST.Dtc NIR TA spectrum (532 nm excitation) in ns time delays (LT) TIPS_tet_Gel_532exc_NIR_LT.Dtc Vis TA spectrum (520 nm excitation) in fs time delays (fsTA) TIPS_tet_NPs_gel_530exc_fsTA_Vis.cor Time resolved emission scan (TRES) (TIPS-tet_NPs_tres_500-750nm_470exc) TIPS-tet_NPs_tres_500-750nm_470exc.cor