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dc.contributor.authorPoh, Jian-Siangen
dc.contributor.authorTran, Duc Nen
dc.contributor.authorBattilocchio, Claudioen
dc.contributor.authorHawkins, Joel Men
dc.contributor.authorLey, Stevenen
dc.date.accessioned2015-06-03T11:11:51Z
dc.date.available2015-06-03T11:11:51Z
dc.date.issued2015-05-26en
dc.identifier.citationAngewandte Chemie International Edition (English) 2015. Volume 127, Issue 27, pages 8031–8034, June 26, 2015. DOI: 10.1002/ange.201501538en
dc.identifier.issn0044-8249
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/248205
dc.description.abstractA copper-catalysed coupling reaction between flow generated unstabilised diazo compounds and terminal alkynes providing di- and tri-substituted allenes is reported. This extremely mild and rapid transformation is highly tolerant of several functional groups.
dc.description.sponsorshipWe are grateful to the Cambridge Home and European Scholarship Scheme (JSP), Swiss National Science Foundation (DNT), Pfizer Worldwide Research and Development (CB and JMH) and EPSRC (SVL, grant nº EP/K0099494/1 and nº EP/K039520/1) for financial support.
dc.languageEnglishen
dc.language.isoenen
dc.publisherWiley
dc.rightsAttribution 2.0 UK: England & Wales
dc.rightsCreative Commons Attribution License 2.0 UK
dc.rights.urihttp://creativecommons.org/licenses/by/2.0/uk/
dc.subjectAlleneen
dc.subjectCarbeneen
dc.subjectDiazoverbindungenen
dc.subjectDurchflusschemieen
dc.subjectKupferen
dc.titleA versatile room temperature route to di- and tri-substituted allenes via flow generated diazo compoundsen
dc.typeArticle
dc.description.versionThis is the final published version. It first appeared at http://onlinelibrary.wiley.com/doi/10.1002/ange.201501538/abstract.en
prism.endingPage8034
prism.publicationDate2015en
prism.publicationNameAngewandte Chemie International Edition (English)en
prism.startingPage8031
prism.volume127en
dc.rioxxterms.funderEPSRC
dc.rioxxterms.projectidEP/K0099494/1
dc.rioxxterms.projectidEP/K039520/1
rioxxterms.versionofrecord10.1002/ange.201501538en
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserveden
rioxxterms.licenseref.startdate2015-05-26en
dc.contributor.orcidLey, Steven [0000-0002-7816-0042]
rioxxterms.typeJournal Article/Reviewen
pubs.funder-project-idEPSRC (EP/K039520/1)
rioxxterms.freetoread.startdate2016-05-26


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Attribution 2.0 UK: England & Wales
Except where otherwise noted, this item's licence is described as Attribution 2.0 UK: England & Wales