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Revealing Invisible Photonic Inscriptions: Images from Strain.


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Authors

Ding, Tao 
Cao, Guoshuai 
Schäfer, Christian G 
Zhao, Qibin 
Gallei, Markus 

Abstract

Photonic structural materials have received intensive interest and have been strongly developed over the past few years for image displays, sensing, and anticounterfeit materials. Their "smartness" arises from their color responsivity to changes of environment, strain, or external fields. Here, we introduce a novel invisible photonic system that reveals encrypted images or characters by simply stretching, or immersing in solvents. This type of intriguing photonic material is composed of regularly arranged core-shell particles that are selectively cross-linked by UV irradiation, giving different strain response compared to un-cross-linked regions. The images reversibly appear and disappear when cycling the strain and releasing it. The unique advantages of this soft polymer opal system compared with other types of photonic gels are that it can be produced in roll to roll quantities, can be vigorously deformed to achieve strong color changes, and has no solvent evaporation issues because it is a photonic rubber system. We demonstrate potential applications together with a fabrication procedure which is straightforward and scalable, vital for user take-up. Our work deepens understanding of this rubbery photonic system based on core-shell nanospheres.

Description

Keywords

patterns, photonic crystals, strains, structural colors, tunable

Journal Title

ACS Appl Mater Interfaces

Conference Name

Journal ISSN

1944-8244
1944-8252

Volume Title

7

Publisher

American Chemical Society (ACS)
Sponsorship
Engineering and Physical Sciences Research Council (EP/E040241/1)
Engineering and Physical Sciences Research Council (EP/G060649/1)
Engineering and Physical Sciences Research Council (EP/H027130/1)
Engineering and Physical Sciences Research Council (EP/K028510/1)
Engineering and Physical Sciences Research Council (EP/L027151/1)
European Research Council (320503)
European Research Council (280078)
We acknowledge financial support from EPSRC grant EP/G060649/1, EP/I012060/1, EP/J007552/1, ERC grant LINASS 320503, EMATTER 280078.