Show simple item record

dc.contributor.authorSalinas-Castillo, Alfonsoen
dc.contributor.authorCalahorro, Antonio Jen
dc.contributor.authorBriones, Daviden
dc.contributor.authorFairen-Jiménez, Daviden
dc.contributor.authorGándara, Felipeen
dc.contributor.authorMendicute-Fierro, Claudioen
dc.contributor.authorSeco, José Men
dc.contributor.authorPérez-Mendoza, Manuelen
dc.contributor.authorFernández, Belénen
dc.contributor.authorRodríguez-Diéguez, Antonioen
dc.date.accessioned2015-07-08T10:35:04Z
dc.date.available2015-07-08T10:35:04Z
dc.date.issued2015-02-25en
dc.identifier.citationSalinas-Castillo et al. New Journal of Chemistry (2015), Vol. 39, pp. 3982-3986. DOI: 10.1039/C5NJ00011Den
dc.identifier.issn1144-0546
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/248859
dc.description.abstractWe designed and synthesized two new metal-organic-frameworks (MOFs) using the novel N-(2-tetrazolethyl)-4'-glycine spacer (TeGly)^2-. We report the in situ formation of cadmium- and zinc-based MOFs using hydrothermal routes. The cadmium-based MOF shows a bidimensional network with luminescence emission while the zinc-based MOF exhibits a three-dimensional structure with gismondine topology and intense blue-greenish photoluminescence emission at room temperature in the solid state. In addition, the porosity of the Zn-based MOF has been fully characterized using a combination of computational methods and experimental techniques.
dc.description.sponsorshipThis work was supported by the MEC of Spain (Project CTQ2011-24478) and the Junta de Andalucía (FQM-1484). D. F.-J. thanks the Royal Society for a University Research Fellowship.
dc.languageEnglishen
dc.language.isoenen
dc.publisherRoyal Society of Chemistry
dc.title2D-cadmium MOF and gismondine-like zinc coordination network based on the N-(2-tetrazolethyl)-4′-glycine linkeren
dc.typeArticle
dc.description.versionThis is the author accepted manuscript. The final version is available from the Royal Society of Chemistry via http://dx.doi.org/10.1039/C5NJ00011Den
prism.endingPage3986
prism.publicationDate2015en
prism.publicationNameNew Journal of Chemistryen
prism.startingPage3982
prism.volume39en
rioxxterms.versionofrecord10.1039/C5NJ00011Den
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserveden
rioxxterms.licenseref.startdate2015-02-25en
dc.identifier.eissn1369-9261
rioxxterms.typeJournal Article/Reviewen
rioxxterms.freetoread.startdate2016-02-25


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record