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dc.contributor.authorGruber, Mathiasen
dc.contributor.authorJung, Seok-Heonen
dc.contributor.authorSchott, Samen
dc.contributor.authorVenkateshvaran, Deepaken
dc.contributor.authorKronemeijer, Aukeen
dc.contributor.authorAndreasen, Jens Wenzelen
dc.contributor.authorMcNeill, Chrisen
dc.contributor.authorWong, Wallace Wing Hoen
dc.contributor.authorShahid, Munazzaen
dc.contributor.authorHeeney, Martinen
dc.contributor.authorLee, Jin-Kyunen
dc.contributor.authorSirringhaus, Henningen
dc.date.accessioned2015-09-04T09:25:44Z
dc.date.available2015-09-04T09:25:44Z
dc.date.issued2015-08-12en
dc.identifier.citationChemical Science 2015, 6: 6949-6960. doi:10.1039/C5SC01326Gen
dc.identifier.issn2041-6520
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/250492
dc.description.abstractIn this article we discuss the synthesis of four new low band-gap co-polymers based on the diketopyrrolopyrrole (DPP) and benzotriazole (BTZ) monomer unit. We demonstrate that the BTZ unit allows for additional solubilizing side-chains on the co-monomer and show that the introduction of a linear side-chain on the DPP-unit leads to an increase in thin-film order and charge-carrier mobility if a sufficiently solubilizing, branched, side chain is attached to the BTZ. We compare two different synthetic routes, direct arylation and Suzuki-polycondensation, and show that direct arylation produces polymers with lower electrical performance. Furthermore we demonstrate that a polymer utilizing this design motif and synthesized via Suzuki-polycondensation ((l C18) DPP (b C17) BTZ) exhibits exceptionally high and near balanced average electron and hole mobilities > 2 cm2/Vs which are among the highest, robustly extracted mobility values reported for DPP copolymers in a top-gate configuration to date. Our results demonstrate clearly that linear side chain substitution of the DPP unit together with co-monomers that allow for the use of sufficiently long or branched solubilizing side chains can be an attractive design motif for solution processable, high mobility DPP copolymers.
dc.description.sponsorshipThe authors gratefully acknowledge funding from the Engineering and Physical Sciences Research Council (EPSRC) through a program grant (EP/G060738/1). J.K.L. and S.H.J. thank the National Research Foundation of Korea (Grant No. 2011-0012274) funded by the Korean government (MEST). C.R.M. acknowledges support from the Australian Research Council (FT100100275). This research was undertaken in part on the SAXS/ WAXS beamline at the Australian Synchrotron, Victoria, Australia.
dc.languageEnglishen
dc.language.isoenen
dc.publisherRoyal Society of Chemistry
dc.rightsAttribution 2.0 UK: England & Wales
dc.rightsCreative Commons Attribution License 2.0 UK
dc.rights.urihttp://creativecommons.org/licenses/by/2.0/uk/
dc.titleEnabling high-mobility, ambipolar charge-transport in a DPP-Benzotriazole copolymer by side chain engineeringen
dc.typeArticle
dc.description.versionThis is the final version of the article. It first appeared from the Royal Society of Chemistry via http://dx.doi.org/10.1039/C5SC01326Gen
prism.endingPage6960
prism.publicationDate2015en
prism.publicationNameChemical Scienceen
prism.startingPage6949
prism.volume6en
dc.rioxxterms.funderEPSRC
dc.rioxxterms.projectidEP/G060738/1
dcterms.dateAccepted2015-08-07en
rioxxterms.versionofrecord10.1039/C5SC01326Gen
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserveden
rioxxterms.licenseref.startdate2015-08-12en
dc.contributor.orcidSchott, Sam [0000-0001-7387-3644]
dc.contributor.orcidVenkateshvaran, Deepak [0000-0002-7099-7323]
dc.contributor.orcidSirringhaus, Henning [0000-0001-9827-6061]
dc.identifier.eissn2041-6539
rioxxterms.typeJournal Article/Reviewen
pubs.funder-project-idEPSRC (EP/G060738/1)


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Attribution 2.0 UK: England & Wales
Except where otherwise noted, this item's licence is described as Attribution 2.0 UK: England & Wales