Structural, electronic and optical properties of m-plane (In,Ga)N/GaN quantum wells: Insights from experiment and atomistic theory
Physical Review B
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Schulz, S., Tanner, D., O'Reilly, E., Caro, M., Martin, T., Bagot, P., Moody, M., et al. (2015). Structural, electronic and optical properties of m-plane (In,Ga)N/GaN quantum wells: Insights from experiment and atomistic theory. Physical Review B, 92 (235419)https://doi.org/10.1103/PhysRevB.92.235419
In this paper we present a detailed analysis of the structural, electronic and optical properties of an m-plane (In,Ga)N/GaN quantum well (QW) structure grown by metal organic vapor phase epitaxy. The sample has been structurally characterized by X-ray diffraction, scanning transmission electron microscopy and 3D atom probe tomography. The optical properties of the sample have been studied by photoluminescence (PL), time-resolved PL spectroscopy and polarized PL excitation spectroscopy (P-PLE). The PL spectrum consisted of a very broad PL line with a high degree of optical linear polarization. To understand the optical properties we have performed atomistic tight-binding calculations, and based on our initial atom probe tomography data, the model includes the effects of strain and built-in field variations arising from random alloy fluctuations. Furthermore, we included Coulomb effects in the calculations. Our microscopic theoretical description reveals strong hole wave function localization effects due to random alloy fluctuations, resulting in strong variations in ground state energies and consequently the corresponding transition energies. This is consistent with the experimentally observed broad PL peak. Furthermore, when including Coulomb contributions in the calculations we find strong exciton localization effects which explain the form of the PL decay transients. Additionally, the theoretical results confirm the experimentally observed high degree of optical linear polarization. Overall, the theoretical data is in very good agreement with the experimental findings, highlighting the strong impact of the microscopic alloy structure on the optoelectronic properties of these systems.
This work was supported by Science Foundation Ireland (project numbers 13/SIRG/2210 and 10/IN.1/I2994), the United Kingdom Engineering and Physical Sciences Research Council (grant agreement nos.: EP\J001627\1 and EP\J003603\1), the European Union 7th Framework Programme DEEPEN (grant agreement no.: 604416), and in part by the European Research Council under the European Community’s Seventh Framework Programme (FP7/2007-2013)/ERC grant agreement no 279361 (MACONS). We like to acknowledge the help of D. Hanley, University of Oxford, on the APT results. S. S. acknowledges computing resources provided by Science Foundation Ireland (SFI) to the Tyndall National Institute and by the SFI and Higher Education Authority Funded Irish Centre for High End Computing.
European Research Council (279361)
External DOI: https://doi.org/10.1103/PhysRevB.92.235419
This record's URL: https://www.repository.cam.ac.uk/handle/1810/252662
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Licence URL: http://creativecommons.org/licenses/by-nc/2.0/uk/
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