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SERS of Individual Nanoparticles on a Mirror: Size Does Matter, but so Does Shape.

Published version
Peer-reviewed

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Authors

Benz, Felix 
Salmon, Andrew 
de Nijs, Bart 

Abstract

Coupling noble metal nanoparticles by a 1 nm gap to an underlying gold mirror confines light to extremely small volumes, useful for sensing on the nanoscale. Individually measuring 10 000 of such gold nanoparticles of increasing size dramatically shows the different scaling of their optical scattering (far-field) and surface-enhanced Raman emission (SERS, near-field). Linear red-shifts of the coupled plasmon modes are seen with increasing size, matching theory. The total SERS from the few hundred molecules under each nanoparticle dramatically increases with increasing size. This scaling shows that maximum SERS emission is always produced from the largest nanoparticles, irrespective of tuning to any plasmonic resonances. Changes of particle facet with nanoparticle size result in vastly weaker scaling of the near-field SERS, without much modifying the far-field, and allows simple approaches for optimizing practical sensing.

Description

Keywords

0306 Physical Chemistry (incl. Structural), 1007 Nanotechnology, Nanotechnology, Bioengineering

Journal Title

J Phys Chem Lett

Conference Name

Journal ISSN

1948-7185
1948-7185

Volume Title

7

Publisher

American Chemical Society (ACS)
Sponsorship
Engineering and Physical Sciences Research Council (EP/G060649/1)
Engineering and Physical Sciences Research Council (EP/L027151/1)
European Research Council (320503)
Engineering and Physical Sciences Research Council (EP/K028510/1)
Engineering and Physical Sciences Research Council (EP/H007024/1)
Engineering and Physical Sciences Research Council (Grant ID: EP/G060649/1)