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Spin signatures of exchange-coupled triplet pairs formed by singlet fission

Accepted version
Peer-reviewed

Type

Article

Change log

Authors

Bayliss, SL 
Weiss, LR 
Friend, RH 
Chepelianskii, AD 

Abstract

We study the effect of an exchange interaction on the magnetic-field-dependent photoluminescence in singlet fission materials. We show that, for strongly interacting triplet exciton pairs (intertriplet exchange interaction greater than the intratriplet spin-dipolar interaction), quantum beating and magnetic-field effects vanish apart from at specific magnetic fields where singlet and quintet levels are mixed by a level anticrossing. We characterize these effects and show that the absence of a magnetic-field effect or zero-field quantum beats does not necessarily mean that fission is inoperative. These results call for a reconsideration of the observations that are considered hallmarks of singlet fission and demonstrate how the spin coherence and exchange coupling of interacting triplet pairs can be measured through magneto-photoluminescence experiments.

Description

Keywords

5108 Quantum Physics, 51 Physical Sciences

Journal Title

Physical Review B

Conference Name

Journal ISSN

2469-9950
2469-9969

Volume Title

94

Publisher

American Physical Society (APS)
Sponsorship
Engineering and Physical Sciences Research Council (EP/M005143/1)
Engineering and Physical Sciences Research Council (EP/G060738/1)
Engineering and Physical Sciences Research Council (EP/M006360/1)
Engineering and Physical Sciences Research Council (Grant ID: EP/G060738/1)