Tensile residual stresses at the surface of welded components are known to compromise fatigue resistance through the accelerated initiation of microcracks, especially at the weld toe. Inducement of compression in these regions is a common technique employed to enhance fatigue performance. Transformation plasticity has been established as a viable method to generate such compressive residual stresses in steel welds and exploits the phase transformation in welding filler alloys, that transform at low temperature to compensate for accumulated thermal contraction strains. Neutron and X-ray diffraction have been used to determine the stress profiles that exist across the surface of plates welded with low transformation temperature welding alloys, with a particular focus on the stress at the weld toe. For the first time, near-surface neutron diffraction data have shown the extent of local stress variation at the critical, fusion boundary location. Compression was evident for the three measurement orientations at the fusion boundaries. Compressive longitudinal residual stresses and tensile trans- verse stresses were measured in the weld metal.