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dc.contributor.authorReisner, Erwinen
dc.contributor.authorRosser, Timothyen
dc.date.accessioned2017-03-27T07:53:25Z
dc.date.available2017-03-27T07:53:25Z
dc.identifier.issn2155-5435
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/263239
dc.description.abstractMolecular catalysis of fuel-forming half reactions such as proton and CO$_2$ reduction is a key area of study for achieving electrical-to-chemical energy storage and solar fuel synthesis. Immobilization of these molecular catalysts on electrode surfaces often results in high turnover numbers and selectivities, even under the challenging conditions of an aqueous environment. This Perspective considers how the combination of electrochemistry and electronic spectroscopy can be used to characterize catalytic processes $\textit{in operando}$, explaining the observed performance and therefore guiding the design principles for the next generation of material/molecule hybrid electrodes and devices. Numerous immobilization strategies and electrode materials are already available, of which wide band gap metal oxides offer transparency to visible light and are therefore ideal for spectroelectrochemical characterization. Spectroscopic analysis of emerging catalytic metal−organic framework and polymer films is also discussed.
dc.description.sponsorshipEPSRC, Christian Doppler Research Association (Austrian Federal Ministry of Science, Research and Economy and the National Foundation for Research, Technology and Development)
dc.language.isoenen
dc.publisherAmerican Chemical Society
dc.rightsAttribution 4.0 Internationalen
dc.rightsAttribution 4.0 Internationalen
dc.rightsAttribution 4.0 Internationalen
dc.rightsAttribution 4.0 Internationalen
dc.rightsAttribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.subjectspectroelectrochemistryen
dc.subjectproton reductionen
dc.subjectCO2 reductionen
dc.subjectelectrocatalysisen
dc.subjectmolecular catalysisen
dc.titleUnderstanding Immobilized Molecular Catalysts for Fuel-Forming Reactions through UV/Vis Spectroelectrochemistryen
dc.typeArticle
prism.endingPage3141
prism.issueIdentifier5en
prism.publicationNameACS Catalysisen
prism.startingPage3131
prism.volume7en
dc.identifier.doi10.17863/CAM.8545
dcterms.dateAccepted2017-03-21en
rioxxterms.versionofrecord10.1021/acscatal.7b00326en
rioxxterms.versionVoRen
rioxxterms.licenseref.urihttp://creativecommons.org/licenses/by/4.0/en
rioxxterms.licenseref.startdate2017-03-21en
dc.contributor.orcidReisner, Erwin [0000-0002-7781-1616]
dc.identifier.eissn2155-5435
rioxxterms.typeJournal Article/Reviewen
pubs.funder-project-idEPSRC (1235150)
pubs.funder-project-idChristian Doppler Forschungsgesellschaft (unknown)
cam.issuedOnline2017-03-21en
cam.orpheus.successThu Jan 30 10:20:26 GMT 2020 - The item has an open VoR version.*
rioxxterms.freetoread.startdate2100-01-01


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Attribution 4.0 International
Except where otherwise noted, this item's licence is described as Attribution 4.0 International