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dc.contributor.authorSmalley, APen
dc.contributor.authorCuthbertson, JDen
dc.contributor.authorGaunt, Matthewen
dc.date.accessioned2017-07-20T10:48:11Z
dc.date.available2017-07-20T10:48:11Z
dc.date.issued2017-02en
dc.identifier.issn0002-7863
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/265676
dc.description.abstractThe design of an enantioselective Pd(II)-catalyzed C-H amination reaction is described. The use of a chiral BINOL phosphoric acid ligand enables the conversion of readily available amines into synthetically valuable aziridines in high enantiomeric ratios. The aziridines can be derivatized to afford a range of chiral amine building blocks incorporating motifs readily encountered in pharmaceutically relevant molecules.
dc.languageengen
dc.language.isoenen
dc.publisherAmerican Chemical Society
dc.titlePalladium-Catalyzed Enantioselective C-H Activation of Aliphatic Amines Using Chiral Anionic BINOL-Phosphoric Acid Ligandsen
dc.typeArticle
prism.endingPage1415
prism.issueIdentifier4en
prism.publicationDate2017en
prism.publicationNameJournal of the American Chemical Societyen
prism.startingPage1412
prism.volume139en
dc.identifier.doi10.17863/CAM.11896
dcterms.dateAccepted2016-12-19en
rioxxterms.versionofrecord10.1021/jacs.6b12234en
rioxxterms.versionAMen
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserveden
rioxxterms.licenseref.startdate2017-02en
dc.contributor.orcidGaunt, Matthew [0000-0002-7214-608X]
dc.identifier.eissn1520-5126
rioxxterms.typeJournal Article/Reviewen
pubs.funder-project-idEPSRC (EP/I00548X/1)
cam.issuedOnline2017-01-09en
rioxxterms.freetoread.startdate2018-01-09


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