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Anchoring ultrafine metallic and oxidized Pt nanoclusters on yolk-shell TiO2 for unprecedentedly high photocatalytic hydrogen production

Accepted version
Peer-reviewed

Type

Article

Change log

Authors

Jin, J 
Wang, C 
Ren, XN 
Huang, SZ 
Wu, M 

Abstract

We demonstrate an alkali modification process to produce highly dispersed ultrafine Pt nanoclusters with metallic Pt0 and oxidized Pt2+ species as co-catalyst anchored on nanosheet-constructed yolk-shell TiO2 (NYTiO2-Pt) acting as light harvesting reactor for highly efficient photocatalytic H2 production. Benefiting from the high surface area, highly dispersed ultrafine Pt nanoclusters (~0.6 nm) with Pt0 and Pt2+ species and special nanosheet-constructed yolk-shell structure, this novel light harvesting reactor exhibits excellent performance for photocatalytic H2 production. The NYTiO2-Pt-0.5 (0.188 wt% Pt) demonstrates an unprecedentedly high H2 evolution rate of 20.88 mmol h−1 g−1 with excellent photocatalytic stability, which is 87 times than that of NYTiO2-Pt-3.0 (0.24 mmol h−1 g−1, 1.88 wt% Pt), and also much higher than those of other TiO2 nanostructures with the same Pt content. Such H2 evolution rate is the highest reported for photocatalytic H2 production with such a low Pt content under simulated solar light. Our strategy here suggests that via alkali modifying the photocatalysts, we can not only enhance the H2 production for solar energy conversion but also significantly decrease the noble metal content for cost saving.

Description

Keywords

nanosheet-constructed yolk-shell TiO2, alkali modification, Pt nanoclusters, Pt0 and Pt2+, photocatalytic H2 production

Journal Title

Nano Energy

Conference Name

Journal ISSN

2211-2855
2211-3282

Volume Title

38

Publisher

Elsevier
Sponsorship
Royal Academy of Engineering (RAEng) (10216/105)
B. L. Su acknowledges the Chinese Central Government for an “Expert of the State” position in the Program of the “Thousand Talents” and a Life Membership at the Clare Hall, Cambridge and the financial support of the Department of Chemistry, University of Cambridge. Y. Li acknowledges Hubei Provincial Department of Education for the “Chutian Scholar” program. T. H. acknowledges support from the Royal Academy of Engineering through a Research Fellowship and an EPSRC Impact acceleration grant. This work is supported by the National Key Research and Development Program of China (2016YFA0202602), Program for Changjiang Scholars and Innovative Research Team in University (IRT_15R52), International Science & Technology Cooperation Program of China (2015DFE52870), National Natural Science Foundation of China (51302204 and 51502225) and the Fundamental Research Funds for the Central Universities (WUT: 2016 029).