Continuous Production of Cellulose Microbeads via Membrane Emulsification
Accepted version
Peer-reviewed
Repository URI
Repository DOI
Change log
Authors
Abstract
© 2017 American Chemical Society. We report on the continuous manufacturing of cellulose microbeads as a sustainable alternative to plastic microparticles, currently used in a wide range of consumer products from toothpaste to paints. Plastic microbeads are not retained by, or degraded in, wastewater treatment plants (due to their size and composition), accumulating in the environment in general and aquatic life in particular, eventually finding their way into the human food supply chain. Here, it is demonstrated, for the first time, that a cross-flow membrane emulsification-phase inversion process can be used to generate stabilized microdroplets of cellulose dissolved in an organic electrolyte solution (1-ethyl-3-methylimidazolium acetate:DMSO) in a sunflower oil-Span 80 continuous phase. The emulsion is subsequently coagulated with an antisolvent, resulting in the formation of solid, spherical, and biodegrad able cellulose microbeads. A systematic analysis of process parameters (continuous and disperse phase flow rate, viscosity, and applied pressure) allowed the determination of a regime within which microspheres can be predictably produced using a 10 μm pore-sized porous glass membrane. Cross-linking of the cellulose beads with glyoxal led to a 3-fold increase in compressive strength of the beads, broadening the potential range of applications where these biodegradable particles could replace current environmentally persistent materials.
Description
Keywords
Journal Title
Conference Name
Journal ISSN
2168-0485