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Nonradiative Losses in Metal Halide Perovskites

Accepted version
Peer-reviewed

Type

Article

Change log

Authors

Stranks, SD 

Abstract

Metal halide perovskites are generating enormous interest for their use in solar cells and light-emission applications. One property linking the high performance of these devices is a high radiative efficiency of the materials; indeed, a prerequisite for these devices to reach their theoretical efficiency limits is the elimination of all nonradiative decay. Despite remarkable progress, there exists substantial parasitic nonradiative recombination in thin films of the materials and when interfaced into devices, and the origin of these processes is still poorly understood. In this Perspective, I will highlight key observations of these parasitic pathways on both the macro- and microscale in thin films and full devices. I will summarize our current understanding of the origin of nonradiative decay, as well as existing solutions that hint at facile ways to remove these processes. I will also show how these nonradiative decay pathways are intimately related to ionic migration, leading to the tantalizing conclusion that eliminating one phenomenon could in turn remove the other, ultimately pushing devices to their theoretical limits.

Description

Keywords

3403 Macromolecular and Materials Chemistry, 34 Chemical Sciences, 3406 Physical Chemistry

Journal Title

ACS Energy Letters

Conference Name

Journal ISSN

2380-8195
2380-8195

Volume Title

2

Publisher

American Chemical Society
Sponsorship
European Commission (622630)
This work has received funding from the People Programme (Marie Curie Actions) of the European Union’s Seventh Framework Programme (FP7/2007-2013) under REA grant agreement number PIOF-GA-2013-622630.