Repository logo
 

Magnetic properties of monoclinic lanthanide metaborates, Ln(BO2)3, Ln  =  Pr, Nd, Gd, Tb

Published version
Peer-reviewed

Type

Article

Change log

Authors

Mukherjee, Paromita  ORCID logo  https://orcid.org/0000-0001-5121-6280
Suard, E 
Dutton, SE 

Abstract

The bulk magnetic properties of the lanthanide metaborates, Ln(BO2)3, Ln = Pr, Nd, Gd, Tb are studied using magnetic susceptibility, heat capacity and isothermal magnetisation measurements. They crystallise in a monoclinic structure containing chains of magnetic Ln3+ and could therefore exhibit features of low-dimensional magnetism and frustration. Pr(BO2)3 is found to have a non-magnetic singlet ground state. No magnetic ordering is observed down to 0.4 K for Nd(BO2)3. Gd(BO2)3 exhibits a sharp magnetic transition at 1.1 K, corresponding to three-dimensional magnetic ordering. Tb(BO2)3 shows two magnetic ordering features at 1.05 K and 1.95 K. A magnetisation plateau at a third of the saturation magnetisation is seen at 2 K for both Nd(BO2)3 and Tb(BO2)3 which persists in an applied field of 14 T. This is proposed to be a signature of quasi one-dimensional behaviour in Nd(BO2)3 and Tb(BO2)3.

Description

Keywords

lanthanide metaborate, monoclinic, quasi-1D, magnetic properties

Journal Title

Journal of Physics: Condensed Matter

Conference Name

Journal ISSN

0953-8984
1361-648X

Volume Title

29

Publisher

IoP Publishing
Sponsorship
Engineering and Physical Sciences Research Council (EP/M000524/1)
We acknowledge funding support from the Winton Programme for the Physics of Sustainability. Magnetic measurements were carried out using the Advanced Materials Characterisation Suite, funded by EPSRC Strategic Equipment Grant EP/M000524/1.
Relationships
Is supplemented by: