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Adsorptive graphene doping: Effect of a polymer contaminant

Published version
Peer-reviewed

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Authors

Arter, WE 
D'Arsié, L 
Wu, X 
Esconjauregui, S 
Robertson, J 

Abstract

© 2017 Author(s). Transfer-induced contamination of graphene and the limited stability of adsorptive dopants are two of the main issues faced in the practical realization of graphene-based electronics. Herein, we assess the stability of HNO3, MoO3, and AuCl3 dopants upon transferred graphene with different extents of polymer contamination. Sheet resistivity measurements prove that polymer residues induce a significantly degenerative effect in terms of doping stability for HNO3 and MoO3 and a highly stabilizing effect for AuCl3. Further characterization by Raman spectroscopy and atomic force microscopy (AFM) provides insight into the stability mechanism. Together, these findings demonstrate the relevance of contamination in the field of adsorptive doping for the realization of graphene-based functional devices.

Description

Keywords

40 Engineering, 51 Physical Sciences, 5104 Condensed Matter Physics

Journal Title

Applied Physics Letters

Conference Name

Journal ISSN

0003-6951
1077-3118

Volume Title

110

Publisher

AIP Publishing
Sponsorship
Engineering and Physical Sciences Research Council (EP/L015978/1)