A versatile hard-soft N/S-ligand for metal coordination and cluster formation.
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Authors
Benson, Callum
Plajer, Alex J
García-Rodríguez, Raúl
Singh, Sanjay
Gade, Lutz H
Publication Date
2016-08-11Journal Title
Chem Commun (Camb)
ISSN
1359-7345
Publisher
Royal Society of Chemistry (RSC)
Volume
52
Issue
62
Pages
9683-9686
Language
eng
Type
Article
This Version
AM
Physical Medium
Print-Electronic
Metadata
Show full item recordCitation
Benson, C., Plajer, A. J., García-Rodríguez, R., Bond, A., Singh, S., Gade, L. H., & Wright, D. (2016). A versatile hard-soft N/S-ligand for metal coordination and cluster formation.. Chem Commun (Camb), 52 (62), 9683-9686. https://doi.org/10.1039/c6cc04805f
Abstract
Deprotonation of the thialdiphosphazane [S[double bond, length as m-dash]PH(μ-N(t)Bu)]2 with a range of metal-bases gives the stable dianion [S-P(μ-N(t)Bu)]2(2-), which is valence-isoelectronic with the widely-used [RN-P(μ-NR)]2(2-) ligand. Structural studies show that the new ligand has adaptable hard-soft character with respect to the coordinated metal centre and that its multidentate nature can be exploited to construct large cage architectures.
Sponsorship
Engineering and Physical Sciences Research Council (EP/K039520/1)
Identifiers
External DOI: https://doi.org/10.1039/c6cc04805f
This record's URL: https://www.repository.cam.ac.uk/handle/1810/270378
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