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dc.contributor.authorBenson, Callum GM
dc.contributor.authorPlajer, Alex J
dc.contributor.authorGarcía-Rodríguez, Raúl
dc.contributor.authorBond, Andrew D
dc.contributor.authorSingh, Sanjay
dc.contributor.authorGade, Lutz H
dc.contributor.authorWright, Dominic S
dc.date.accessioned2018-01-09T12:41:08Z
dc.date.available2018-01-09T12:41:08Z
dc.date.issued2016-08-11
dc.identifier.issn1359-7345
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/270378
dc.description.abstractDeprotonation of the thialdiphosphazane [S[double bond, length as m-dash]PH(μ-N(t)Bu)]2 with a range of metal-bases gives the stable dianion [S-P(μ-N(t)Bu)]2(2-), which is valence-isoelectronic with the widely-used [RN-P(μ-NR)]2(2-) ligand. Structural studies show that the new ligand has adaptable hard-soft character with respect to the coordinated metal centre and that its multidentate nature can be exploited to construct large cage architectures.
dc.format.mediumPrint-Electronic
dc.languageeng
dc.publisherRoyal Society of Chemistry (RSC)
dc.titleA versatile hard-soft N/S-ligand for metal coordination and cluster formation.
dc.typeArticle
prism.endingPage9686
prism.issueIdentifier62
prism.publicationDate2016
prism.publicationNameChem Commun (Camb)
prism.startingPage9683
prism.volume52
dc.identifier.doi10.17863/CAM.17251
rioxxterms.versionofrecord10.1039/c6cc04805f
rioxxterms.versionAM
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserved
rioxxterms.licenseref.startdate2016-08
dc.contributor.orcidBond, Andrew [0000-0002-1744-0489]
dc.contributor.orcidWright, Dominic [0000-0002-9952-3877]
dc.identifier.eissn1364-548X
rioxxterms.typeJournal Article/Review
pubs.funder-project-idEngineering and Physical Sciences Research Council (EP/K039520/1)
cam.issuedOnline2016-07-13


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