A versatile hard-soft N/S-ligand for metal coordination and cluster formation.
dc.contributor.author | Benson, Callum GM | |
dc.contributor.author | Plajer, Alex J | |
dc.contributor.author | García-Rodríguez, Raúl | |
dc.contributor.author | Bond, Andrew D | |
dc.contributor.author | Singh, Sanjay | |
dc.contributor.author | Gade, Lutz H | |
dc.contributor.author | Wright, Dominic S | |
dc.date.accessioned | 2018-01-09T12:41:08Z | |
dc.date.available | 2018-01-09T12:41:08Z | |
dc.date.issued | 2016-08-11 | |
dc.identifier.issn | 1359-7345 | |
dc.identifier.uri | https://www.repository.cam.ac.uk/handle/1810/270378 | |
dc.description.abstract | Deprotonation of the thialdiphosphazane [S[double bond, length as m-dash]PH(μ-N(t)Bu)]2 with a range of metal-bases gives the stable dianion [S-P(μ-N(t)Bu)]2(2-), which is valence-isoelectronic with the widely-used [RN-P(μ-NR)]2(2-) ligand. Structural studies show that the new ligand has adaptable hard-soft character with respect to the coordinated metal centre and that its multidentate nature can be exploited to construct large cage architectures. | |
dc.format.medium | Print-Electronic | |
dc.language | eng | |
dc.publisher | Royal Society of Chemistry (RSC) | |
dc.title | A versatile hard-soft N/S-ligand for metal coordination and cluster formation. | |
dc.type | Article | |
prism.endingPage | 9686 | |
prism.issueIdentifier | 62 | |
prism.publicationDate | 2016 | |
prism.publicationName | Chem Commun (Camb) | |
prism.startingPage | 9683 | |
prism.volume | 52 | |
dc.identifier.doi | 10.17863/CAM.17251 | |
rioxxterms.versionofrecord | 10.1039/c6cc04805f | |
rioxxterms.version | AM | |
rioxxterms.licenseref.uri | http://www.rioxx.net/licenses/all-rights-reserved | |
rioxxterms.licenseref.startdate | 2016-08 | |
dc.contributor.orcid | Bond, Andrew [0000-0002-1744-0489] | |
dc.contributor.orcid | Wright, Dominic [0000-0002-9952-3877] | |
dc.identifier.eissn | 1364-548X | |
rioxxterms.type | Journal Article/Review | |
pubs.funder-project-id | Engineering and Physical Sciences Research Council (EP/K039520/1) | |
cam.issuedOnline | 2016-07-13 |