A [HN(BH=NH)<inf>2</inf>]<sup>2-</sup> Dianion, Isoelectronic with a β-Diketiminate

Less, RJ; Hanf, Schirin; García-Rodríguez, R; Bond, Andrew; Wright, Dominic

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Authors

Less, RJ

Hanf, Schirin

García-Rodríguez, R

Bond, Andrew

Wright, Dominic

Publication Date

2018-03-12

Journal Title

Organometallics

ISSN

0276-7333

Publisher

American Chemical Society

Volume

Issue

Pages

628-631

Type

Article

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Citation

Less, R., Hanf, S., García-Rodríguez, R., Bond, A., & Wright, D. (2018). A [HN(BH=NH)<inf>2</inf>]<sup>2-</sup> Dianion, Isoelectronic with a β-Diketiminate. Organometallics, 37 (5), 628-631. https://doi.org/10.1021/acs.organomet.7b00436

Abstract

The 1:2 reaction of the Al(III) β-diketiminate dihydride [{DMPnacnac}AlH2] (DMPnacnac = HC{C(Me)N(2,6-Me2-C6H3)}2) (1) with ammonia-borane (NH3BH3) gives the new complex [{DMPnacnac}Al{NHBH)2NH}] (3), whose [HN(BHNH)2]2- dianion is isoelectronic with β-diketiminate anions.

Sponsorship

EPSRC (EP/K039520/1)

Identifiers

External DOI: https://doi.org/10.1021/acs.organomet.7b00436

This record's URL: https://www.repository.cam.ac.uk/handle/1810/273446

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