A [HN(BH=NH)2 ]2- Dianion, Isoelectronic with a β-Diketiminate
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Peer-reviewed
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Abstract
The 1:2 reaction of the Al(III) β-diketiminate dihydride [{DMPnacnac}AlH2] (DMPnacnac = HC{C(Me)N(2,6-Me2-C6H3)}2) (1) with ammonia-borane (NH3BH3) gives the new complex [{DMPnacnac}Al{NHBH)2NH}] (3), whose [HN(BHNH)2]2- dianion is isoelectronic with β-diketiminate anions.
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Keywords
3402 Inorganic Chemistry, 34 Chemical Sciences
Journal Title
Organometallics
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Journal ISSN
0276-7333
1520-6041
1520-6041
Volume Title
37
Publisher
American Chemical Society
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Sponsorship
Engineering and Physical Sciences Research Council (EP/K039520/1)