A [HN(BH=NH)<inf>2</inf>]<sup>2-</sup> Dianion, Isoelectronic with a β-Diketiminate

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Authors
Less, RJ
  Hanf, Schirin
García-Rodríguez, R
  Bond, Andrew
  Wright, Dominic
Publication Date
2018-03-12
Journal Title
Organometallics
ISSN
0276-7333
Publisher
American Chemical Society
Volume
37
Issue
5
Pages
628-631
Type
Article
This Version
AM
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Citation
Less, R., Hanf, S., García-Rodríguez, R., Bond, A., & Wright, D. (2018). A [HN(BH=NH)<inf>2</inf>]<sup>2-</sup> Dianion, Isoelectronic with a β-Diketiminate. Organometallics, 37 (5), 628-631. https://doi.org/10.1021/acs.organomet.7b00436
Abstract
The 1:2 reaction of the Al(III) β-diketiminate dihydride [{DMPnacnac}AlH2] (DMPnacnac = HC{C(Me)N(2,6-Me2-C6H3)}2) (1) with ammonia-borane (NH3BH3) gives the new complex [{DMPnacnac}Al{NHBH)2NH}] (3), whose [HN(BHNH)2]2- dianion is isoelectronic with β-diketiminate anions.
Sponsorship
Engineering and Physical Sciences Research Council (EP/K039520/1)
Identifiers
External DOI: https://doi.org/10.1021/acs.organomet.7b00436
This record's URL: https://www.repository.cam.ac.uk/handle/1810/273446
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