Manufacturing Macroporous Monoliths of Microporous Metal-Organic Frameworks
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Peer-reviewed
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Abstract
We report the first use of a pressure-assisted sintering technique on metal-organic framework (MOF) powders allowing for fast production of crystalline macro-porous monoliths. Mechanical and micro-structural characterization of the monoliths is presented. The interconnected macro-porosity of the compacts can be adjusted providing an immense interface for gas-solid interaction. The sintering technique is well-established and commercially available, allowing industrial scale-up of the process.
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Keywords
metal-organic frameworks, zeolitic imidazolate frameworks, porosity, sintering, monoliths
Journal Title
ACS Applied Nano Materials
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Journal ISSN
2574-0970
2574-0970
2574-0970
Volume Title
1
Publisher
American Chemical Society (ACS)
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Royal Society (UF150021)