Hydrolysis of organometallic and metal-amide precursors: synthesis routes to oxo-bridged heterometallic complexes, metal-oxo clusters and metal oxide nanoparticles.
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Publication Date
2018-03-12Journal Title
Dalton Trans
ISSN
1477-9226
Publisher
Royal Society of Chemistry (RSC)
Volume
47
Issue
11
Pages
3638-3662
Language
eng
Type
Article
This Version
AM
Physical Medium
Print
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Garden, J., & Pike, S. (2018). Hydrolysis of organometallic and metal-amide precursors: synthesis routes to oxo-bridged heterometallic complexes, metal-oxo clusters and metal oxide nanoparticles.. Dalton Trans, 47 (11), 3638-3662. https://doi.org/10.1039/c8dt00017d
Abstract
The hydrolysis reaction between Brønsted basic organometallic or metal-amide reagents with Brønsted acidic OH groups from water or metal-hydroxides may act as a controlled stoichiometric strategy for the formation of M-O-M bonds, if careful consideration of reaction conditions is employed. This article explores the utilisation of highly reactive organometallic and metal-amide complexes from across the periodic table as reagents for the synthesis of metal-oxo clusters, oxo-bridged heterobimetallics and metal oxide nanoparticles. Such reactivity typically occurs at low temperatures with the release of hydrocarbon or amine by-products. The impact of ligand coordination, M-C bond strength, M-OH acidity and reaction temperature are discussed.
Identifiers
External DOI: https://doi.org/10.1039/c8dt00017d
This record's URL: https://www.repository.cam.ac.uk/handle/1810/275702
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