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dc.contributor.authorWu, Ke-Jun
dc.contributor.authorGao, Yunhu
dc.contributor.authorTorrente-Murciano, Laura
dc.date.accessioned2018-05-15T08:55:49Z
dc.date.available2018-05-15T08:55:49Z
dc.date.issued2018-09-03
dc.identifier.issn1359-6640
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/275782
dc.description.abstractHollow bimetallic nanoparticles exhibit unique surface plasmonic properties, enhanced catalytic activities and high photo-thermal conversion efficiencies amongst other properties, however, their research and further deployment are currently limited by their complicated multi-step syntheses. This paper presents a novel approach for their continuous synthesis with controllable and tuneable sizes and compositions. This robust manufacturing tool, consisting of coiled flow inverter (CFI) reactors connected in series, allows for the first time the temporal and spatial separation of the initial formation of silver seeds and their subsequent galvanic displacement reaction in the presence of a palladium precursor, leading to the full control of both steps separately. We have also demonstrated that coupling the galvanic replacement and co-reduction leads to a great kinetic enhancement of the system leading to a high yield process of hollow bimetallic nanoparticles, directly applicable to other metal combinations.
dc.format.mediumPrint
dc.languageeng
dc.publisherRoyal Society of Chemistry (RSC)
dc.rightsAttribution 4.0 International
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.titleContinuous synthesis of hollow silver-palladium nanoparticles for catalytic applications.
dc.typeArticle
prism.endingPage441
prism.issueIdentifier0
prism.publicationDate2018
prism.publicationNameFaraday Discuss
prism.startingPage427
prism.volume208
dc.identifier.doi10.17863/CAM.23048
dcterms.dateAccepted2018-02-27
rioxxterms.versionofrecord10.1039/c8fd00001h
rioxxterms.versionVoR
rioxxterms.licenseref.urihttp://creativecommons.org/licenses/by/4.0/
rioxxterms.licenseref.startdate2018-09
dc.contributor.orcidWu, Ke-Jun [0000-0001-8658-5449]
dc.contributor.orcidGao, Yunhu [0000-0001-8483-7892]
dc.contributor.orcidTorrente-Murciano, Laura [0000-0002-7938-2587]
dc.identifier.eissn1364-5498
rioxxterms.typeJournal Article/Review
pubs.funder-project-idEngineering and Physical Sciences Research Council (EP/L020432/2)
cam.issuedOnline2018
cam.orpheus.successThu Jan 30 12:59:46 GMT 2020 - The item has an open VoR version.
rioxxterms.freetoread.startdate2100-01-01


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Attribution 4.0 International
Except where otherwise noted, this item's licence is described as Attribution 4.0 International