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Development of a universal stress sensor for graphene and carbon fibres

Published version
Peer-reviewed

Type

Article

Change log

Authors

Frank, O 
Tsoukleri, G 
Riaz, I 
Papagelis, K 
Parthenios, J 

Abstract

Carbon fibres (CF) represent a significant volume fraction of modern structural airframes. Embedded into polymer matrices, they provide significant strength and stiffness gains over unit weight as compared to other competing structural materials. Nevertheless, no conclusive structural model yet exists to account for their extraordinary properties. In particular, polyacrynonitrile (PAN) derived CF are known to be fully turbostratic: the graphene layers are slipped sideways relative to each other, which leads to an inter-graphene distance much greater than graphite. Here, we demonstrate that CF derive their mechanical properties from those of graphene itself. By monitoring the Raman G peak shift with strain for both CF and graphene, we develop a universal master plot relating the G peak strain sensitivity of all types of CF to graphene over a wide range of tensile moduli. A universal value of - average- shift rate with axial stress of ~ -5{\omega}0^-1 (cm^-1 MPa^-1)is calculated for both graphene and all CF exhibiting annular ("onion-skin") morphology.

Description

Keywords

RAMAN-SPECTROSCOPY, UNIAXIAL-STRESS, GRAPHITE, NANOTUBES, MODULUS, COMPRESSION, COMPOSITES, MONOLAYER, SPECTRUM, BEHAVIOR

Journal Title

NAT COMMUN

Conference Name

Journal ISSN

2041-1723
2041-1723

Volume Title

2

Publisher

Springer Science and Business Media LLC
Sponsorship
Engineering and Physical Sciences Research Council (EP/G042357/1)