Impedance-based sensor for potassium ions.

Authors
Day, C 
Søpstad, S 
Nathan, A 

Loading...
Thumbnail Image
Type
Article
Change log
Abstract

A conductometric sensor for potassium ions in solution is presented. Interdigitated, planar gold electrodes were coated with a potassium-selective polymer membrane composed of a poly(vinyl chloride) matrix with about 65 wt% of plasticiser and 2-5 wt% of a potassium-selective ionophore. The impedance of the membrane was measured, using the electrodes as a transducer, and related to the concentration of potassium in a sample solution in contact with the membrane. Sensitivity was optimised by varying the sensor components, and selectivity for potassium over sodium was also shown. The resulting devices are compact, miniature, robust sensors which, by means of impedance measurements, eliminate the need for a reference electrode. The sensor was tested for potassium concentration changes of 2 mM across the clinically relevant range of 2.7-18.7 mM.

Publication Date
2018-11-30
Online Publication Date
2018-06-20
Acceptance Date
2018-06-15
Keywords
Blood analysis, Conductometric sensor, Impedance spectroscopy, Ion-selective membrane, Portable sensor, Potassium, Electric Impedance, Electrochemical Techniques, Ions, Potassium
Journal Title
Anal Chim Acta
Journal ISSN
0003-2670
1873-4324
Volume Title
1034
Publisher
Elsevier BV
Sponsorship
Kidney Research UK (RP_053_20160307)
Henslow Fellowship, Darwin College, Cambridge L'Oreal -UNESCO UK & Ireland Fellowship For Women In Science