Photoreforming of lignocellulose into H2 using nano-engineered carbon nitride under benign conditions
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Authors
Reisner, E
Kasap, Hatice
Achilleos, Demetra S
Huang, Ailun
Publication Date
2018-09-19Journal Title
Journal of the American Chemical Society
ISSN
1520-5126
Publisher
American Chemical Society
Type
Article
Metadata
Show full item recordCitation
Reisner, E., Kasap, H., Achilleos, D. S., & Huang, A. (2018). Photoreforming of lignocellulose into H2 using nano-engineered carbon nitride under benign conditions. Journal of the American Chemical Society https://doi.org/10.1021/jacs.8b07853
Abstract
Photoreforming of lignocellulose is a promising approach
toward sustainable H2 generation, but this kinetically challenging
reaction currently requires UV-absorbing or toxic light absorbers
under harsh conditions. Here, we report a cyanamide-functionalized
carbon nitride, NCNCNx, which shows enhanced performance
upon ultra-sonication. This activated NCNCNx allows for the
visible-light driven conversion of purified and raw lignocellulose
samples into H2 in the presence of various proton reduction co-catalysts.
The reported room-temperature photoreforming process operates
under benign aqueous conditions (pH ~2-15) without the
need for toxic components.
Keywords
7 Affordable and Clean Energy
Sponsorship
Austrian Federal Ministry for Digital and Economic Affairs, the National Foundation for Research, Technology and Development, OMV
Funder references
Christian Doppler Forschungsgesellschaft (unknown)
Identifiers
External DOI: https://doi.org/10.1021/jacs.8b07853
This record's URL: https://www.repository.cam.ac.uk/handle/1810/285348
Rights
Licence:
http://www.rioxx.net/licenses/all-rights-reserved
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