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dc.contributor.authorNappi, M
dc.contributor.authorGaunt, MJ
dc.date.accessioned2018-12-22T00:31:10Z
dc.date.available2018-12-22T00:31:10Z
dc.date.issued2019
dc.identifier.issn0276-7333
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/287393
dc.description.abstractThis article presents a new class of mild reagents that is capable of oxidizing palladacycle(II) complexes to high-valent palladium species, promoting the formation of C–N bonds in stoichiometric and catalytic conditions. The weak N–O bond and the extremely electron with-drawing benzenesulfonate group on the oxygen atom of the oxidant are crucial moieties to ensure the desired activity. The oxidation mech-anism could involve outer-sphere single electron transfer (SET) processes, opening the possibility for a complementary reactivity of Pd(IV) species.
dc.description.sponsorshipRoyal Society H2020 European Research Council
dc.publisherAmerican Chemical Society (ACS)
dc.titleA Class of N-O-Type Oxidants to Access High-Valent Palladium Species
dc.typeArticle
prism.endingPage148
prism.issueIdentifier1
prism.publicationDate2019
prism.publicationNameOrganometallics
prism.startingPage143
prism.volume38
dc.identifier.doi10.17863/CAM.34697
dcterms.dateAccepted2018-11-13
rioxxterms.versionofrecord10.1021/acs.organomet.8b00712
rioxxterms.versionAM
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserved
rioxxterms.licenseref.startdate2019-01-14
dc.contributor.orcidNappi, M [0000-0002-3023-0574]
dc.contributor.orcidGaunt, MJ [0000-0002-7214-608X]
dc.identifier.eissn1520-6041
rioxxterms.typeJournal Article/Review
pubs.funder-project-idEuropean Commission Horizon 2020 (H2020) Marie Sk?odowska-Curie actions (702462)
pubs.funder-project-idThe Royal Society (wm140104)
pubs.funder-project-idEngineering and Physical Sciences Research Council (EP/N031792/1)
cam.issuedOnline2018-11-21
rioxxterms.freetoread.startdate2019-11-21


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