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Sulfide resorption during crustal ascent and degassing of oceanic plateau basalts.

Published version
Peer-reviewed

Type

Article

Change log

Authors

Jenner, FE 
Smythe, DJ 
Hauri, EH 
Bullock, ES 

Abstract

Mantle plume-related magmas typically have higher chalcophile and siderophile element (CSE) contents than mid-ocean ridge basalts (MORB). These differences are often attributed to sulfide-under-saturation of plume-related melts. However, because of eruption-related degassing of sulfur (S) and the compositional, pressure, temperature and redox effects on S-solubility, understanding the magmatic behavior of S is challenging. Using CSE data for oceanic plateau basalts (OPB), which rarely degas S, we show that many OPB are sulfide-saturated. Differences in the timing of sulfide-saturation between individual OPB suites can be explained by pressure effects on sulfur solubility associated with ascent through over-thickened crust. Importantly, where S-degassing does occur, OPB have higher CSE contents than S-undegassed melts at similar stages of differentiation. This can be explained by resorption of earlier-formed sulfides, which might play an important role in enriching degassed melts in sulfide-compatible CSE and potentially contributes to anomalous enrichments of CSE in the crust.

Description

Keywords

0403 Geology, 0402 Geochemistry

Journal Title

Nat Commun

Conference Name

Journal ISSN

2041-1723
2041-1723

Volume Title

10

Publisher

Springer Science and Business Media LLC
Sponsorship
European Research Council (306655)
Natural Environment Research Council (NE/M011801/2)
Natural Environment Research Council (NE/M000427/1)
Australia-New Zealand IODP Consortium (ANZIC) Cambridge Commonwealth and European Trust