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dc.contributor.authorMcTernan, Charlieen
dc.contributor.authorRonson, Tanyaen
dc.contributor.authorNitschke, Jonathanen
dc.date.accessioned2019-04-26T23:30:34Z
dc.date.available2019-04-26T23:30:34Z
dc.date.issued2019-05en
dc.identifier.issn0002-7863
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/292042
dc.description.abstractWe report the design, synthesis, and post-assembly modification of a new phosphine-paneled supramolecular cage framework, the anion binding ability of which can be modified rationally through selective post-assembly functionalization. The parent phosphine-paneled cage can be modified in situ through oxidation, methylation, or auration. These covalent and coordinative modifications to the exterior of the cage strongly influence the guest-binding properties of the host.
dc.description.sponsorshipEuropean Research Council (695009), UK Engineering and Physical Sciences Research Council (EPSRC, EP/P027067/1,
dc.format.mediumPrint-Electronicen
dc.languageengen
dc.publisherAmerican Chemical Society
dc.rightsAll rights reserved
dc.titlePost-assembly Modification of Phosphine Cages Controls Host-Guest Behavior.en
dc.typeArticle
prism.endingPage6842
prism.issueIdentifier17en
prism.publicationDate2019en
prism.publicationNameJournal of the American Chemical Societyen
prism.startingPage6837
prism.volume141en
dc.identifier.doi10.17863/CAM.39195
dcterms.dateAccepted2019-04-16en
rioxxterms.versionofrecord10.1021/jacs.9b02604en
rioxxterms.versionAM
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserveden
rioxxterms.licenseref.startdate2019-05en
dc.contributor.orcidMcTernan, Charles [0000-0003-1359-0663]
dc.contributor.orcidRonson, Tanya [0000-0002-6917-3685]
dc.contributor.orcidNitschke, Jonathan [0000-0002-4060-5122]
dc.identifier.eissn1520-5126
rioxxterms.typeJournal Article/Reviewen
pubs.funder-project-idEuropean Commission Horizon 2020 (H2020) ERC (695009)
pubs.funder-project-idEPSRC (via University of Manchester) (EP/P027067/1)
cam.orpheus.successThu Jan 30 10:46:05 GMT 2020 - Embargo updated*


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