Show simple item record

dc.contributor.authorLavendomme, Royen
dc.contributor.authorRonson, Tanyaen
dc.contributor.authorNitschke, Jonathanen
dc.date.accessioned2019-07-11T23:30:35Z
dc.date.available2019-07-11T23:30:35Z
dc.date.issued2019-07-23en
dc.identifier.issn0002-7863
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/294567
dc.description.abstractCovalent macrocycles and three-dimensional cages were prepared by the self-assembly of di- or tri-topic ani- lines and 2,6-diformylpyridine subcomponents around palladium(II) templates. The resulting 2,6-bis(imino)pyridyl-PdII motif contains a tridentate ligand leaving a free coordination site on the PdII centers, which points inward. The binding of ligands to the free coordination sites in these assemblies was found to alter the product stability, and multi-topic ligands could be used to control product size. Multi-topic ligands also bridged metallomacrocycles to form higher-order supramo- lecular assemblies, which were characterized via NMR spectroscopy, mass spectrometry and X-ray crystallography. An ef- ficient method was developed to reduce the imine bonds to and cages, which were inaccessible through other means.
dc.description.sponsorshipFondation Wiener-Anspach (FWA). Diamond Light Source - Beamline I19 (MT15768). National Mass Spectrometry Facility at the University of Swansea.
dc.format.mediumPrint-Electronicen
dc.languageengen
dc.publisherAmerican Chemical Society
dc.rightsAll rights reserved
dc.titleMetal and Organic Templates Together Control the Size of Covalent Macrocycles and Cages.en
dc.typeArticle
prism.endingPage12158
prism.issueIdentifier30en
prism.publicationDate2019en
prism.publicationNameJournal of the American Chemical Societyen
prism.startingPage12147
prism.volume141en
dc.identifier.doi10.17863/CAM.41672
dcterms.dateAccepted2019-07-09en
rioxxterms.versionofrecord10.1021/jacs.9b06182en
rioxxterms.versionAM
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserveden
rioxxterms.licenseref.startdate2019-07-23en
dc.contributor.orcidLavendomme, Roy [0000-0001-6238-8491]
dc.contributor.orcidRonson, Tanya [0000-0002-6917-3685]
dc.contributor.orcidNitschke, Jonathan [0000-0002-4060-5122]
dc.identifier.eissn1520-5126
rioxxterms.typeJournal Article/Reviewen
pubs.funder-project-idEuropean Commission Horizon 2020 (H2020) ERC (695009)
pubs.funder-project-idEPSRC (via University of Manchester) (EP/P027067/1)
cam.orpheus.successThu Jan 30 10:43:29 GMT 2020 - Embargo updated*
rioxxterms.freetoread.startdate2020-07-23


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record