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dc.contributor.authorCarpenter, Johnen
dc.contributor.authorMcTernan, Charlieen
dc.contributor.authorRonson, Tanyaen
dc.contributor.authorNitschke, Jonathanen
dc.date.accessioned2019-07-25T23:31:05Z
dc.date.available2019-07-25T23:31:05Z
dc.date.issued2019-07-10en
dc.identifier.issn0002-7863
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/294941
dc.description.abstractHere we describe the formation of a trigonal prismatic cage, utilizing 2‐formyl‐1,8‐naphthyridine subcom‐ ponents to bind pairs of silver(I) ions in close proximity. This cage is the first example of a new class of subcomponent self‐ assembled polyhedral structures having bimetallic vertices, as opposed to the single metal centers that typically serve as structural elements within such cages. Our new cage self‐as‐ sembles around a pair of anionic templates, which are shown by crystallographic and solution‐phase data to bind within the central cavity of the structure. Many different anions serve as competent templates and guests. Elongated dianions, such as the strong oxidizing agent peroxysulfate, also serve to tem‐ plate and bind within the cavity of the prism. The principle of using subcomponents that have more than one spatially close, but non‐chelating, binding site may thus allow access to other higher‐order structures with multi‐metallic vertices.
dc.description.sponsorshipEuropean Research Council (695009) and the UK Engineering and Physical Sciences Re‐ search Council (EPSRC, EP/P027067/1). European Union's Horizon 2020 research and innovation program, Marie Sklodowska‐Curie Grant (642192).
dc.format.mediumPrint-Electronicen
dc.languageengen
dc.publisherAmerican Chemical Society
dc.rightsAll rights reserved
dc.titleAnion Pairs Template a Trigonal Prism with Disilver Vertices.en
dc.typeArticle
prism.endingPage11413
prism.issueIdentifier29en
prism.publicationDate2019en
prism.publicationNameJournal of the American Chemical Societyen
prism.startingPage11409
prism.volume141en
dc.identifier.doi10.17863/CAM.42028
dcterms.dateAccepted2019-07-06en
rioxxterms.versionofrecord10.1021/jacs.9b05432en
rioxxterms.versionAM
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserveden
rioxxterms.licenseref.startdate2019-07-10en
dc.contributor.orcidCarpenter, John [0000-0002-4341-2887]
dc.contributor.orcidMcTernan, Charles [0000-0003-1359-0663]
dc.contributor.orcidRonson, Tanya [0000-0002-6917-3685]
dc.contributor.orcidNitschke, Jonathan [0000-0002-4060-5122]
dc.identifier.eissn1520-5126
rioxxterms.typeJournal Article/Reviewen
pubs.funder-project-idEuropean Commission Horizon 2020 (H2020) ERC (695009)
pubs.funder-project-idEuropean Commission (642192)
pubs.funder-project-idEPSRC (via University of Manchester) (EP/P027067/1)
pubs.funder-project-idIsaac Newton Trust (18.08(c))
pubs.funder-project-idLeverhulme Trust (ECF-2018-684)
cam.orpheus.successThu Jan 30 10:42:53 GMT 2020 - Embargo updated*
rioxxterms.freetoread.startdate2020-07-10


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