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Piezoelectricity and electrostriction in ferroelastic materials with polar twin boundaries and domain junctions

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Peer-reviewed

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Article

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Abstract

jats:pWeak piezoelectricity, compared with electrostriction, occurs in twinned ferroelastic materials even when the uniform bulk material is centro-symmetric. In a simple computer simulation, polarity is exclusively generated by the flexoelectric effect. Simple twinned structures (parallel twin walls) are electrostrictive and show no piezoelectricity. Complex twinned structures break inversion symmetry by the simultaneous appearance of junctions, kinks, needle domains, etc. Such structures show weak piezoelectricity (d ∼ 10−4 pm/V) under periodic boundary conditions together with significant electrostriction. The macroscopic piezoelectric response is stronger (d ∼ 10−3 pm/V) under free boundary conditions due to the effect of relaxing surfaces.</jats:p>

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Keywords

40 Engineering, 4016 Materials Engineering

Journal Title

Applied Physics Letters

Conference Name

Journal ISSN

0003-6951
1077-3118

Volume Title

114

Publisher

AIP Publishing

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All rights reserved
Sponsorship
Engineering and Physical Sciences Research Council (EP/P024904/1)
EPSRC