Repository logo
 

Isostructural Mott transition in 2D honeycomb antiferromagnet V0.9PS3

Published version
Peer-reviewed

Type

Article

Change log

Authors

Son, S 
Daisenberger, D 
Hamidov, H 
Haines, CRS 

Abstract

We present the observation of an isostructural Mott insulator-metal transition in van-der-Waals honeycomb antiferromagnet V0.9PS3 through high-pressure x-ray diffraction and transport measurements. The MPX3 family of magnetic van-der-Waals materials (M denotes a first row transition metal and X either S or Se) are currently the subject of broad and intense attention, but the vanadium compounds have until this point not been studied beyond their basic properties. We observe insulating variable-range-hopping type resistivity in V0.9PS3, with a gradual increase in effective dimensionality with increasing pressure, followed by a transition to a metallic resistivity temperature dependence between 112 and 124 kbar. The metallic state additionally shows a low-temperature upturn we tentatively attribute to the Kondo Effect. A gradual structural distortion is seen between 26-80 kbar, but no structural change at higher pressures corresponding to the insulator-metal transition. We conclude that the insulator-metal transition occurs in the absence of any distortions to the lattice - an isostructural Mott transition in a new class of two-dimensional material, and in strong contrast to the behavior of the other MPX3 compounds.

Description

Keywords

cond-mat.str-el, cond-mat.str-el

Journal Title

npj Quantum Materials

Conference Name

Journal ISSN

2397-4648
2397-4648

Volume Title

4

Publisher

Springer Science and Business Media LLC
Sponsorship
Engineering and Physical Sciences Research Council (EP/E00489X/1)
Engineering and Physical Sciences Research Council (EP/M000524/1)