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On the Changing Role of the Stratosphere on the Tropospheric Ozone Budget: 1979–2010

Accepted version
Peer-reviewed

Type

Article

Change log

Abstract

jats:titleAbstract</jats:title>jats:pWe study the evolution of tropospheric ozone over the period 1979–2010 using a chemistry‐climate model employing a stratosphere‐troposphere chemistry scheme. By running with specified dynamics, the key feedback of composition on meteorology is suppressed, isolating the chemical response. By using historical forcings and emissions, interactions between processes are realistically represented. We use the model to assess how the ozone responds over time and to investigate model responses and trends. We find that the chlorofluorocarbon (CFC)‐driven decrease in stratospheric ozone plays a significant role in the tropospheric ozone burden. Over the period 1979–1994, the decline in transport of ozone from the stratosphere, partially offsets an emissions‐driven increase in tropospheric ozone production. From 1994–2010, despite a leveling off in emissions, increased stratosphere‐to‐troposphere transport of ozone drives a small increase in the tropospheric ozone burden. These results have implications for the impact of future stratospheric ozone recovery on air quality and radiative forcing.</jats:p>

Description

Keywords

tropospheric, ozone, budget, stratosphere-troposphere, transport

Journal Title

Geophysical Research Letters

Conference Name

Journal ISSN

0094-8276
1944-8007

Volume Title

47

Publisher

American Geophysical Union (AGU)

Rights

All rights reserved
Sponsorship
National Centre for Atmospheric Science (NERC) (via University of Leeds) (R8/H12/83/003)
European Commission (603557)
NERC (NE/L002507/1)
European Community’s Seventh Framework Programme 10 (FP7/2007-2013) under grant agreement no. 603557 (StratoClim).