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Rheology of hard glassy materials.

Accepted version
Peer-reviewed

Type

Article

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Authors

Zaccone, A 
Terentjev, EM 

Abstract

Glassy solids may undergo a fluidization (yielding) transition upon deformation whereby the material starts to flow plastically. It has been a matter of debate whether this process is controlled by a specific time scale, from among different competing relaxation/kinetic processes. Here, two constitutive models of cage relaxation are examined within the microscopic model of nonaffine elasto-plasticity. One (widely used) constitutive model implies that the overall relaxation rate is dominated by the fastest between the structural (α) relaxation rate and the shear-induced relaxation rate. A different model is formulated here which, instead, assumes that the slowest (global) relaxation process controls the overall relaxation. We show that the first model is not compatible with the existence of finite elastic shear modulus for quasistatic (low-frequency) deformation, while the second model is able to describe all key features of deformation of 'hard' glassy solids, including the yielding transition, the nonaffine-to-affine plateau crossover, and the rate-stiffening of the modulus. The proposed framework provides an operational way to distinguish between 'soft' glasses and 'hard' glasses based on the shear-rate dependence of the structural relaxation time.

Description

Keywords

amorphous materials, glasses, metallic glass, disordered systems, rheology, yielding

Journal Title

J Phys Condens Matter

Conference Name

Journal ISSN

0953-8984
1361-648X

Volume Title

32

Publisher

IOP Publishing

Rights

All rights reserved
Sponsorship
Engineering and Physical Sciences Research Council (EP/F032773/1)
Engineering and Physical Sciences Research Council (EP/J017639/1)
US Army ARO Cooperative Agreement W911NF-19-2-0055 EPSRC Theory of Condensed Matter Critical Mass Grant EP/J017639