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dc.contributor.authorJagt, Robert Aen
dc.contributor.authorHuq, Tahmida Nen
dc.contributor.authorHill, Sam Aen
dc.contributor.authorThway, Maungen
dc.contributor.authorLiu, Tianyuanen
dc.contributor.authorNapari, Marien
dc.contributor.authorRoose, Barten
dc.contributor.authorGałkowsk, Krzysztofen
dc.contributor.authorLi, Weiweien
dc.contributor.authorLin, Serena Fenen
dc.contributor.authorStranks, Samuelen
dc.contributor.authorMacManus-Driscoll, Judith Len
dc.contributor.authorHoye, Robert LZen
dc.date.accessioned2020-06-24T23:31:35Z
dc.date.available2020-06-24T23:31:35Z
dc.identifier.issn2380-8195
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/307242
dc.description.abstractPerovskite solar cells (PSCs) with transparent electrodes can be integrated with existing solar panels in tandem configurations to increase the power conversion efficiency. A critical layer in semi-transparent PSCs is the inorganic buffer layer, which protects the PSC against damage when the transparent electrode is sputtered on top. The development of n-i-p structured semi-transparent PSCs has been hampered by the lack of suitable p-type buffer layers. In this work we develop a p-type CuOx buffer layer, which can be grown uniformly over the perovskite device without damaging the perovskite or organic hole transport layer. The CuOx layer has high hole mobility (4.3 ± 2 cm2 V-1 s-1), high transmittance (>95%), and a suitable ionization potential for hole extraction (5.3 ± 0.2 eV). Semi-transparent PSCs with efficiencies up to 16.7% are achieved using the CuOx buffer layer. Our work demonstrates a new approach to integrate n-i-p structured PSCs into tandem configurations, as well as enable the development of other devices that need high quality, protective p-type layers.
dc.description.sponsorshipEPSRC Department Training Partnership studentship (No: EP/N509620/1), as well as Bill Welland. T.N.H. acknowledges funding from the EPSRC Centre for Doctoral Training in Graphene Technology (No. EP/L016087/1) and the Aziz Foundation. W.-W.L. and J.L.M.-D. acknowledge support from the EPSRC (Nos.: EP/L011700/1, EP/N004272/10), and the Isaac Newton Trust (Minute 13.38(k)). M.N. and J.L.M.-D. acknowledge financial support from EPSRC (No. EP/P027032/1). S. D. S. acknowledges support from the Royal Society and Tata Group (UF150033). R.L.Z.H. acknowledges support from the Royal Academy of Engineering under the Research Fellowship scheme (No.: RF\201718\1701), the Centre of Advanced Materials for Integrated Energy Systems (EPSRC Grant No. EP/P007767/1), the Isaac Newton Trust (Minute 19.07(d)), and the Kim and Juliana Silverman Research Fellowship at Downing College, Cambridge.
dc.publisherAmerican Chemical Society
dc.rightsAll rights reserved
dc.subjectphysics.app-phen
dc.subjectphysics.app-phen
dc.titleRapid Vapor-Phase Deposition of High-Mobility p-Type Buffer Layers on Perovskite Photovoltaics for Efficient Semi-Transparent Devicesen
dc.typeArticle
prism.publicationNameACS Energy Lettersen
dc.identifier.doi10.17863/CAM.54339
dcterms.dateAccepted2020-06-22en
rioxxterms.versionofrecord10.1021/acsenergylett.0c00763en
rioxxterms.versionAM
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserveden
rioxxterms.licenseref.startdate2020-06-22en
dc.contributor.orcidRoose, Bart [0000-0002-0972-1475]
dc.contributor.orcidLi, Weiwei [0000-0001-5781-5401]
dc.contributor.orcidStranks, Samuel [0000-0002-8303-7292]
dc.identifier.eissn2380-8195
rioxxterms.typeJournal Article/Reviewen
pubs.funder-project-idRoyal Society (UF150033)
pubs.funder-project-idEPSRC (EP/L011700/1)
pubs.funder-project-idLeverhulme Trust (RPG-2015-017)
pubs.funder-project-idEPSRC (EP/N004272/1)
pubs.funder-project-idEPSRC (EP/P007767/1)
pubs.funder-project-idEPSRC (EP/N509620/1)
pubs.funder-project-idEPSRC (EP/P027032/1)
pubs.funder-project-idEPSRC (EP/L016087/1)
pubs.funder-project-idEPSRC (EP/T02030X/1)
cam.issuedOnline2020-06-22en
cam.orpheus.successMon Jun 29 08:55:37 BST 2020 - Embargo updated*
rioxxterms.freetoread.startdate2021-06-22


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