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Electrolysis: What textbooks don’t tell us

Accepted version
Peer-reviewed

Type

Article

Change log

Authors

Chang, Hasok 
Kim, Kihyang 

Abstract

We present a critical discussion of how chemistry textbooks treat the electrolysis of water and aqueous salt solutions, based on a survey of general chemistry textbooks in English and Korean at secondary and tertiary levels, also informed by the historical background of 19th-century debates. English-language textbooks present various and contradictory accounts of the electrolysis of water; a key point of disagreement is whether hydrogen and oxygen gases originate from pre-existing H+and OHions, or from the direct reduction and oxidation of H2O molecules. School textbooks in South Korea all present the same account, with no indication of alternative views. A vast majority of all texts ignore the possibility that H2and O2may result from secondary reactions, which was a standard view in the late 19th century following the works of Daniell and Miller. Concerning the electrolysis of aqueous salt solutions, all texts give oversimplified views of competing reactions based on standard reduction/oxidation potentials. It is understandable that textbooks try to present sufficiently simple pictures that students at each level can handle; however, this should not be done in a way that shuts down questions. We recommend that students should be made aware that textbook accounts are only models, and encouraged to extend their learning beyond the models. The plausibility of our recommendations is shown in a pilot study we conducted with secondary school students in South Korea.

Description

Keywords

40 Engineering, 4010 Engineering Practice and Education, 7 Affordable and Clean Energy

Journal Title

Chemistry Education Research and Practice

Conference Name

Journal ISSN

1109-4028
1756-1108

Volume Title

21

Publisher

Royal Society of Chemistry (RSC)

Rights

All rights reserved
Sponsorship
British Academy (WP160055)