Dataset

This data set contains all of the data presented in the paper "'Metal-Organic Framework and Inorganic Glass Composites', L. Longley et. al, Nature Comms, Accepted”. This consists of structure and property data characterising a new class of hybrid glass – inorganic glass composites composed of glassy ZIF-62, [Zn(Im)1.75(bIm)0.25] (Im = C3H3N2− and bIm = C7H5N2−) and a series of aluminophosphate glasses of general formula (1−x)([Na2O]z[P2O5])-x([AlO3/2][AlF3]y). The structure of these composites is determined via powder X-ray diffraction (PXRD), energy dispersive X-ray spectroscopy (EDX), attenuated total reflectance infra-red spectroscopy (ATR-IR), Raman spectroscopy, scanning electron microscopy (SEM), light microscopy, 1H and 31P nuclear magnetic resonance (NMR), density measurements and X-ray total-scattering. The thermal properties during composite formation where characterised by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The mechanical properties and ionic conductivity of the composites were investigated via nano-indentation and impedance spectroscopy respectively. Each sub folder contains README files for each data collection technique explaining its contents and the methodology by which the data was gathered.

Standard word processor, spreadsheet or database programs, or otherwise stated in the readme files.